Issue 8, 1978

Unusual stereoselectivities in olefin metathesis

Abstract

The stereoselectivity of metathesis of various olefins (cis- or trans-RCH[double bond, length half m-dash]CHMe) decreases with increasing bulk of the R groups; this corresponds to an increased randomness of the various modes of olefin co-ordination to the metallo-carbene intermediate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 341-342

Unusual stereoselectivities in olefin metathesis

M. Leconte, J. L. Bilhou, W. Reimann and J. M. Basset, J. Chem. Soc., Chem. Commun., 1978, 341 DOI: 10.1039/C39780000341

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