The ratio of the quantum yields for the formation of Mo(CO)5 by u.v. photolysis of Mo(CO)6, and its destruction by visible light, has been measured for CH4, Ar and CO matrices. The ratio shows a large dependence on the matrix material. The mechanistic implications of this dependence are discussed.
M. Poliakoff, J. Chem. Soc., Faraday Trans. 2, 1977, 73, 569 DOI: 10.1039/F29777300569
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