Reactions of methyl(4-tolyl)metal derivatives with various electrophilic reagents give preferential cleavage of the methyl–metal bond in cis-[PtMe(4-MeC6H4)(PMe2Ph)2] but the 4-tolyl–metal bond in [PtMe(4-MeC6H4)(cyclo-octa-1,5-diene)] and in cis-[AuMe2(4-MeC6H4)(PPh3)].
J. K. Jawad and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1977, 892 DOI: 10.1039/C39770000892
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