The reaction of deuterium and neopentane catalysed by a sintered platinum film has been shown to yield appreciable amounts of monodeuteriated isopentane; this result strongly supports a mechanism involving an adsorbed alkyl species as the intermediate in the isomerization of small hydrocarbons.
Z. Karpiński and L. Guczi, J. Chem. Soc., Chem. Commun., 1977, 563 DOI: 10.1039/C39770000563
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