Tris(trifluorosilyl)phosphine, the first perfluoro compound of phosphorus and silicon, has been synthesized in high yield from the mercury-sensitized photolysis of Si2F6 with PF3.
K. G. Sharp, J. Chem. Soc., Chem. Commun., 1977, 564 DOI: 10.1039/C39770000564
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