NN-Dichloroalkylamines (RNCl2) undergo thermal decomposition in gas chromatography at 215–260 °C giving alkenes and N-chloroimines, from secondary, and nitriles predominantly, with a minor amount of alkenes, from primary.
J. T. Roberts, P. Kovacic, J. A. Tonnis and F. V. Scalzi, J. Chem. Soc., Chem. Commun., 1977, 418 DOI: 10.1039/C39770000418
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