Photolysis of the bis-benzaldehyde (6) results in simultaneous formation of rings B and D of the rhoeadine skeleton and leads directly to (±)-cis-alpinigenine (1a).
S. Prabhakar, A. M. Lobo and I. M. C. Oliveira, J. Chem. Soc., Chem. Commun., 1977, 419 DOI: 10.1039/C39770000419
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