The reaction of N-propyl-1,4-dihydronicotinamide (PNAH) with ferricyanide ion follows a secondorder rate law with rate =k[Fe(CN)63–][PNAH], ΔH‡ 2 kcal mol–1, ΔS‡–43 cal mol–1 K–1 and an observed kinetic deuterium isotope effect, kH/kD, of 1·68.
T. Okamoto, A. Ohno and S. Oka, J. Chem. Soc., Chem. Commun., 1977, 181 DOI: 10.1039/C39770000181
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