The double bond migration of 2-methylbut-1-ene on MoS2 occurs predominantly by a carbonium ion mechanism, while isomerization and hydrogen exchange of other olefins proceed through σ-alkyl intermediates.
T. Okuhara, K. Tanaka and K. Tanabe, J. Chem. Soc., Chem. Commun., 1977, 180 DOI: 10.1039/C39770000180
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