Unambiguous syntheses of key intermediates establish that the biosynthesis of aspulvinone (6) from (1)via(3) in Aspergillus terreus proceeds by selective mono-prenylation of (1) leading to intermediate (2a) and by selective ‘chromanation’ of (3) leading to intermediate (4)
D. W. Knight and G. Pattenden, J. Chem. Soc., Chem. Commun., 1976, 635 DOI: 10.1039/C39760000635
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