In the reaction of cis-[Mo(CO)2(Me2PCH2CH2-PMe 2)2] with alkyl halides, electron transfer from the metal substrate to the addendum involves the oxidation of Mo0 to MoII with MoI as the identified paramagnetic intermediate.
J. A. Connor and P. I. Riley, J. Chem. Soc., Chem. Commun., 1976, 634 DOI: 10.1039/C39760000634
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