The e.s.r. parameters and half-lives at 25 °C for several persistent selenoalkyl radicals, RnMSeĊBut2, which have the RnM group eclipsed by the Cα2pz Orbital, are reported: the 13Cα and 77Se hyperfine splittings are dependent on the electronegativity, rather than on the size, of RnM.
J. C. Scaiano and K. U. Ingold, J. Chem. Soc., Chem. Commun., 1976, 205 DOI: 10.1039/C39760000205
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