It is shown by 1H, 13C, and 31P n.m.r. spectroscopy that the preferred conformation of ethyldichlorophosphine and isopropyldichlorophosphine around the P–C bond is that in which a methyl group and the phosphorus lone pair are trans to each other.
J. P. Dutasta and J. B. Robert, J. Chem. Soc., Chem. Commun., 1975, 747 DOI: 10.1039/C39750000747
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