SCHEDULED MAINTENANCE:
Copper-catalysed thermal reactions of methyl diazoacetate with acetylenic sulphides gives (alkynylthio)-acetates, possibly via an acetylenic sulphonium ylide; the reactivity of the acetylenic sulphides is higher than that of diethyl sulphide.
W. Ando, H. Higuchi and T. Migita, J. Chem. Soc., Chem. Commun., 1974, 523a DOI: 10.1039/C3974000523A
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