Relative rates of ethoxy exchange in 4-substituted diethylcyclohexane-1,1-dicarboxylates. Validation of the use of 4-t-butyl derivatives as reactivity models in the kinetic method of conformational analysis of cyclohexanes

James McKenna; Jean M. McKenna; Barrie G. Hutley

doi:10.1039/C39740000522

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Relative rates of ethoxy exchange in 4-substituted diethylcyclohexane-1,1-dicarboxylates. Validation of the use of 4-t-butyl derivatives as reactivity models in the kinetic method of conformational analysis of cyclohexanes

James McKenna, Jean M. McKenna and Barrie G. Hutley

Abstract

A 4-t-butyl group has no effect on the observed rate of ethoxy exchange in diethylcyclohexane-1,1-dicarboxylates, a significant result in relation to the validity of the usual kinetic method for conformational analysis of cyclohexanes.

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DOI: https://doi.org/10.1039/C39740000522
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1974, 522-523

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Relative rates of ethoxy exchange in 4-substituted diethylcyclohexane-1,1-dicarboxylates. Validation of the use of 4-t-butyl derivatives as reactivity models in the kinetic method of conformational analysis of cyclohexanes

J. McKenna, J. M. McKenna and B. G. Hutley, J. Chem. Soc., Chem. Commun., 1974, 522 DOI: 10.1039/C39740000522

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Journal of the Chemical Society, Chemical Communications

Relative rates of ethoxy exchange in 4-substituted diethylcyclohexane-1,1-dicarboxylates. Validation of the use of 4-t-butyl derivatives as reactivity models in the kinetic method of conformational analysis of cyclohexanes

Abstract

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Relative rates of ethoxy exchange in 4-substituted diethylcyclohexane-1,1-dicarboxylates. Validation of the use of 4-t-butyl derivatives as reactivity models in the kinetic method of conformational analysis of cyclohexanes

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