The e.s.r. spectra of phenylphosphoranyl radicals [PhnPX3 –nY]· show that, depending on the nature of X and Y, these radicals fall into two types in which the unpaired electron is centred mainly on phosphorus or on the aromatic ring.
A. G. Davies, M. J. Parrott and B. P. Roberts, J. Chem. Soc., Chem. Commun., 1974, 973 DOI: 10.1039/C39740000973
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