Issue 17, 1974

Transition-metal complexes of methylenecyclopropanes: ring-opening reactions promoted by palladium(II)

Abstract

A variety of stable 1,2-η-bonded methylene cyclopropane complexes of RhI, IrI, Pto, and PtII are reported; isomers of Feist's acid dimethyl ester react with PdCl2(MeCN)2 to yield 1,3-enyl complexes of palladium-(II); stable alkyl complexes of PdII; containing β-hydrogen atoms are reported, and their stability is discussed.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 686-688

Transition-metal complexes of methylenecyclopropanes: ring-opening reactions promoted by palladium(II)

M. Green and R. P. Hughes, J. Chem. Soc., Chem. Commun., 1974, 686 DOI: 10.1039/C39740000686

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