Issue 17, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Preparation and X-ray crystallographic characterisation of an unusual heteronuclear complex, RhAg2(C[triple bond, length half m-dash]CC6F5)5(PPh3)3

Omar M. Abu Salah,   Michael I. Bruce,   Melvyn Rowen Churchill  and  Barry G. DeBoer  

Abstract

The complex RhAg2(C[triple bond, length half m-dash]CC6F5)5(PPh3)3, prepared from RhCl(PPh3)3 and Ag(C[triple bond, length half m-dash]CC6F5), contains a central rhodium atom which is octahedrally co-ordinated to one PPh3 ligand and five σ-acetylide units; each PPh3Ag group is π-bonded to three acetylenic bonds (one acetylenic linkage thereby being involved with both silver atoms); rhodium–silver distances are 3.086(1) and 3.102(1)Å.

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Article information

DOI
https://doi.org/10.1039/C39740000688
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 688-689

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Preparation and X-ray crystallographic characterisation of an unusual heteronuclear complex, RhAg2(C[triple bond, length half m-dash]CC6F5)5(PPh3)3

O. M. A. Salah, M. I. Bruce, M. R. Churchill and B. G. DeBoer, J. Chem. Soc., Chem. Commun., 1974, 688 DOI: 10.1039/C39740000688

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