Issue 10, 1974

Positional selectivity in aromatic nitration occurring at the diffusion rate

Abstract

Nitration of pseudocumene (1,2,4-trimethyl-benzene) produces 5- and 6-nitropseudocumenes in the ratio 9:1 under conditions where there is evidence that both C-5 and C-6 are activated sufficiently to react upon encounter, showing the necessity for including in the kinetic scheme an intermediate preceding Wheland intermediate formation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 382-383

Positional selectivity in aromatic nitration occurring at the diffusion rate

R. B. Moodie, K. Schofield and J. B. Weston, J. Chem. Soc., Chem. Commun., 1974, 382 DOI: 10.1039/C39740000382

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