Isomeric bicyclic methylenecyclopropanes, obtained from carbenoid ring contraction of bicyclic cyclobutanones, exhibit extraordinarily clean thermal equilibria which is entropy-controlled near the boundaries of Bredt's rule.
A. S. Kende and E. E. Riecke, J. Chem. Soc., Chem. Commun., 1974, 383 DOI: 10.1039/C39740000383
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