The monoglucuronosides of 19-hydroxy- and 19-oxo-3β-hydroxyandrost-5-en-17-one have been prepared by the Koenigs–Knorr procedure. Steiic effects in these reactions are compared with those encountered in the preparation of the corresponding sulphates.
S. H. Nicholson, D. S. H. Smith and A. B. Turner, J. Chem. Soc., Perkin Trans. 1, 1973, 2887 DOI: 10.1039/P19730002887
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