Silver difluorosulphoximide and rhenium pentacarbonyl bromide react to give Re(CO)5NSOF2; heating of the product to 90 °C yields the dimeric species [Re(CO)4NSOF2]2, with bridging NSOF2-groups; with Mn(CO)5Br, only the dimer was isolated.
R. Mews and O. Glemser, J. Chem. Soc., Chem. Commun., 1973, 823 DOI: 10.1039/C39730000823
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