Issue 16, 1973

Mechanism of methoxyphenylcarbene insertion into Group IV element–hydrogen bonds via a chromium carbene complex

Abstract

Activation parameters indicate that the first-order component of the kinetic equation corresponds not to complete dissociation of the carbene ligand but rather to the production of an intermediate which is also formed in the kinetically dominant second-order process of the concerted reaction described in the title.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1973, 578-579

Mechanism of methoxyphenylcarbene insertion into Group IV element–hydrogen bonds via a chromium carbene complex

J. A. Connor, J. P. Day and R. M. Turner, J. Chem. Soc., Chem. Commun., 1973, 578 DOI: 10.1039/C39730000578

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