Further substitution (X) in the pendant ring of lignans of the 1-aryltetrahydronaphthalene type [e.g.(1)] leads to increased strain in ring B and in the lactone function, as a result of which solvolysis reactions at C(4) are accelerated and the base-catalysed opimerisation at C(2), which occurs readily in the natural precursors, is not observed.
D. C. Ayres and C. K. Lim, J. Chem. Soc., Chem. Commun., 1973, 487 DOI: 10.1039/C39730000487
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...