The ratio of products, 2-(4-cyanophenyl)-1,1-dimethylhydrazine (I) and 5-cyano-2-dimethyl-3H-azepine (II), which is obtained from the photolysis of p-cyanophenyl azide in dimethylamine is wavelength dependent; this wavelength effect is rationalized in terms of excess of excitation energy producing a hot nitrene.
R. A. Odum and G. Wolf, J. Chem. Soc., Chem. Commun., 1973, 360 DOI: 10.1039/C39730000360
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