Treatment of an alkene with a thallium(I) carboxylate and iodine gives the corresponding α-iodocarboxylate in high yield, thereby affording a regiospecific and inexpensive modification for the Prevost reaction.
R. C. Cambie, R. C. Hayward, J. L. Roberts and P. S. Rutledge, J. Chem. Soc., Chem. Commun., 1973, 359 DOI: 10.1039/C39730000359
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