α-Substituted methallyl p-tolyl sulphoxides undergo a [2,3]-sigmatropic rearrangement to allylic sulphenate esters (II) which can be intercepted by suitable nucleophiles, thus providing a new stereospecific route to trisubstituted olefins.
P. A. Grieco, J. Chem. Soc., Chem. Commun., 1972, 702a DOI: 10.1039/C3972000702A
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