The reaction of π-C5H5Fe(CO)2P(CF3)2 with nitric oxide gives π-C5H5Fe(CO)2P(O)(CF3)2, while with sulphur, π-C5H5Fe(CO)2P(S)(CF3)2 is formed; on irradiation, π-C5H5Fe(CO)2P(CF3)2 dimerises to give the expected phosphido-bridged complex, whereas the oxide and sulphide produce (C5H5)2Fe3(CO)2[OP(CF3)2]4 and π-C5H5Fe(CO)2SP(S)(CF3)2, respectively.
R. C. Dobbie, P. R. Mason and R. J. Porter, J. Chem. Soc., Chem. Commun., 1972, 612 DOI: 10.1039/C39720000612
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