Issue 10, 1972

Some reactions of a co-ordinated phosphido-group

Abstract

The reaction of π-C5H5Fe(CO)2P(CF3)2 with nitric oxide gives π-C5H5Fe(CO)2P(O)(CF3)2, while with sulphur, π-C5H5Fe(CO)2P(S)(CF3)2 is formed; on irradiation, π-C5H5Fe(CO)2P(CF3)2 dimerises to give the expected phosphido-bridged complex, whereas the oxide and sulphide produce (C5H5)2Fe3(CO)2[OP(CF3)2]4 and π-C5H5Fe(CO)2SP(S)(CF3)2, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 612-613

Some reactions of a co-ordinated phosphido-group

R. C. Dobbie, P. R. Mason and R. J. Porter, J. Chem. Soc., Chem. Commun., 1972, 612 DOI: 10.1039/C39720000612

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements