Tetrakis(dialkylamido)molybdenum(IV) compounds Mo(NR2)4(R = Me, Et) have been isolated from reactions of MoCl5 and LiNR2. The dimethylamide is a purple crystalline sublimable compound which is diamagnetic. The spectroscopic properties (electronic, vibrational, n.m.r.) are discussed in terms of a distorted tetrahedral configuration (D2d).
D. C. Bradley and M. H. Chisholm, J. Chem. Soc. A, 1971, 2741 DOI: 10.1039/J19710002741
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