Some metal complexes of morpholine-4-carbodithioate

Abstract

Morpholine-4-carbodithioate (mdtc) complexes of titanium(IV), vanadium(IV), chromium(III), manganese(III), iron(III), cobalt(III), nickel(II), copper(II), zinc(II), and cadmium(II) have been prepared and characterised by analysis and magnetic and spectroscopic techniques. The complexes are of the type M(mdtc)_n, where n is the oxidation state of the metal ion except for vanadium(IV), where the complexing species is the VO²⁺ ion. Some adducts with the parent base morpholine are also reported.