Thallium(III)-induced bromination of meta-substituted anisoles shows a surprising preference for attack para to the ether function even in the presence of bulky ortho-substituents in contrast to what is expected on the basis of the presumed steric requirements of the attacking species.
K. L. Erickson and H. W. Barowsky, J. Chem. Soc. D, 1971, 1596 DOI: 10.1039/C29710001596
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