X-Ray structure analysis of Pt(PPh3)2(C3H4) shows that, unlike in other transition-metal–allene complexes in which allene is perpendicular to the co-ordination plane, allene is in the co-ordination plane.
M. Kadonaga, N. Yasuoka and N. Kasai, J. Chem. Soc. D, 1971, 1597 DOI: 10.1039/C29710001597
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