Both the free base and its conjugate acid, of the reduced form of certain azaviolenes, react with the oxidized form to generate a stable radical ion, but the rate approaches the diffusion-controlled limit only with the free base.
C. F. Bernasconi, R. G. Bergstrom and S. Hünig, J. Chem. Soc. D, 1971, 1485 DOI: 10.1039/C29710001485
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