The novel tetramethylcyclobutadiene complex [PtCF3(C4Me4)(PMe2Ph)2]+[PF6]– and the first platinum(IV)–alkoxy-carbene complex [PtMe2(CF3)-([graphic omitted]H2)(PMe2Ph)2]+[PF6]– have been prepared from cationic acetylenic intermediates.
M. H. Chisholm and H. C. Clark, J. Chem. Soc. D, 1971, 1484 DOI: 10.1039/C29710001484
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