The reaction, BPh4–+ 2IrCl62–+ H2O → Ph2BOH + Ph2+ 2IrCl63–+ H+, has been shown to occur quantitatively in aqueous solution; the kinetics are interpreted in terms of a mechanism involving BPh4˙ radicals which are also proposed as intermediates in certain electrochemical and photochemical reactions of BPh4–.
P. Abley and J. Halpern, J. Chem. Soc. D, 1971, 1238 DOI: 10.1039/C29710001238
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...