The 93Nb n.m.r. spectra of mixtures of NbCl5 and NbBr5 were examined, and all of the seven possible species of niobium(V) halides were found to be present in the concentrations expected for random halogen distribution.
Yu. A. Buslaev, V. D. Kopanev and V. P. Tarasov, J. Chem. Soc. D, 1971, 1175 DOI: 10.1039/C29710001175
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