The relative intensities of bands in the Raman spectra of transition-metal carbonyls in the 200 cm–1 region are anomalous and indicate that the bond derived polarisability tensor elements are of opposite sign along and transverse to the CO bond axis.
S. F. A. Kettle, I. Paul and P. J. Stamper, J. Chem. Soc. D, 1970, 1724 DOI: 10.1039/C29700001724
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