Issue 3, 1970

Oxidation of molybdenum carbonyl and related derivatives by organic halides; thermal and photochemical activation

Abstract

The thermal reaction between Mo(CO)6 and CCl4 in ethyl acetate solution at 80° involves intermediate formation of Mo(CO)5EtOAc (I), which is successively oxidised to MoI and MoV derivatives, the step Mo0→ MoI being mainly responsible for free-radical formation: (I) prepared photochemically reacts similarly with CBr4 at room temperature.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 144b-146

Oxidation of molybdenum carbonyl and related derivatives by organic halides; thermal and photochemical activation

C. H. Bamford, G. C. Eastmond and F. J. T. Fildes, J. Chem. Soc. D, 1970, 144b DOI: 10.1039/C2970000144B

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