The oxidation of Mo(CO)6 by CBr4 in ethyl acetate at 80° can proceed rapidly by a chain process which is strongly inhibited by olefinic additives: it is suggested that the chain carriers are CBr3 radicals.
C. H. Bamford, G. C. Eastmond and F. J. T. Fildes, J. Chem. Soc. D, 1970, 146 DOI: 10.1039/C29700000146
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