Vanadyl acetylacetonate interacts with 1,4-dioxan in methylene dichloride solution, and a complex [VO(acac)2]2(dioxan), C24H40O12V2, has been isolated; a dioxan molecule bridges two VO(acac)2 groups by co-ordination to the sixth ‘unoccupied’ site of the vanadium atom.
K. Dichmann, G. Hamer, S. C. Nyburg and W. F. Reynolds, J. Chem. Soc. D, 1970, 1295 DOI: 10.1039/C29700001295
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