The signs of the quadrupole coupling constants, e2qQ, in the compounds SnF2, SnO, SnS, Sn3(PO4)2, and SnC2O4 have been determined to resolve inconsistencies in the literature, and all have a positive value, implying that the dominant contribution to the electricfield gradient arises from the pz electron density in the non-bonding orbital.
T. C. Gibb, B. A. Goodman and N. N. Greenwood, J. Chem. Soc. D, 1970, 774 DOI: 10.1039/C29700000774
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