Thermal decomposition of vinylidene fluoride behind reflected shock waves
Abstract
Thermolysis of dilute mixtures of 1,1-C2H2F2 in argon in a single-pulse shock tube at 1290–1480K, 440kN m–2 total pressure, and reaction times of ca. 1 ms yields monofluoroacetylene with an activation energy of ca. 335 kJ mol–1.