The bonding mode of co-ordinated thiocyanate ion in solution has been observed to be dependent upon the nature of the solvent, Pd–SCN bonding being promoted by solvents having high dielectric constants, and a mixture of Pd–NCS, Pd–SCN, and Pd–SCN–Pd bonding being formed in solvents having low dielectric constants.
J. L. Burmeister, R. L. Hassel and R. J. Phelan, J. Chem. Soc. D, 1970, 679 DOI: 10.1039/C29700000679
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