The mass spectrometry of benzo[b]selenophen, of its 2- and 3-methyl homologues, and of benzo[b]selenophen-2-aldehyde has been investigated. Whilst the fragmentation of these compounds follows the pattern of the corresponding benzo[b]thiophens, the benzo[b]selenophens proved relatively more fragile, selenium being easily split off.
N. P. Buu-Hoï, M. Mangane, M. Renson and L. Christiaens, J. Chem. Soc. B, 1969, 971 DOI: 10.1039/J29690000971
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