Hydrogen and methane are formed in the pyrolysis of trimethylsilane by radical non-chain mechanisms, rate-determined by the dissociation of silicon-hydrogen and silicon–methyl bonds; radical disproportionations leading ultimately to cyclic products are important, but reactions forming silenes apparently are not.
I. M. T. Davidson and C. A. Lambert, J. Chem. Soc. D, 1969, 1276 DOI: 10.1039/C29690001276
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