The first crystal structure of a copper complex of a sulphur-containing amino-acid, bis(methioninato)copper(II), has shown that the sulphur atom is not co-ordinated to the metal ion, suggesting a possible model for trans-methylation reactions.
M. V. Veidis and G. J. Palenik, J. Chem. Soc. D, 1969, 1277 DOI: 10.1039/C29690001277
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