Issue 0, 1968

Stereochemical studies. Part XLVII. Conformational analysis of many-membered ring compounds. The cyclododecenes

Abstract

The equilibrium has been determined for an eight-component system of position- and cistrans-isomeric 1,1,4,4-tetramethylcyclododecenes; enthalpies of hydrogenation have been measured for the cis- and trans-1,1,4,4-tetramethylcyclododec-8-ene pair; large differences in the relative stabilities and hydrogenation enthalpies have been found. The results are discussed in conformational terms and possible conformations of the cis- and trans-cyclododecenes are considered.

Article information

Article type
Paper

J. Chem. Soc. B, 1968, 441-447

Stereochemical studies. Part XLVII. Conformational analysis of many-membered ring compounds. The cyclododecenes

J. Sicher, M. Svoboda, B. J. Mallon and R. B. Turner, J. Chem. Soc. B, 1968, 441 DOI: 10.1039/J29680000441

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