Irradiation of acetyl chloride in the gas phase with light from a medium-pressure mercury-vapour lamp leads to the formation of carbon monoxide, methyl chloride, vinyl chloride, and polymer. The energy of activation for the formation of methyl chloride is 15·5 ± 0·5 kcal. mole–1 and that for the formation of vinyl chloride is 20·4 ± 0·5 kcal. mole–1.
W. D. Capey, J. R. Majer and J. C. Robb, J. Chem. Soc. B, 1968, 447 DOI: 10.1039/J29680000447
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