The vibrational spectra of a number of normal and deuteriated pentammine and tetrammine cobalt(III) complexes involving MO4n– ligands have been measured (M = P, S, Cr, or Mo), and from the observed splitting of the MO4n– vibrations it is confirmed that the chromate and molybdate groups, like sulphate, can function as mono- or bidentate ligands in cobaltammines.
R. Coomber and W. P. Griffith, J. Chem. Soc. A, 1968, 1128 DOI: 10.1039/J19680001128
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