Issue 0, 1968

Structure and reactivity of transition-metal complexes with polyatomic ligands. Part V. Electron spin resonance spectra of intermediates and some kinetic results for the acid hydrolysis of [Cr(CN)5NO]3–

Abstract

Three intermediates in the acid hydrolysis of [Cr(CN)5NO]3– are detected in solution by e.s.r. at room temperature, the final product being [Cr(NO)(H2O)5]2+. Each species is characterised by different A(14N), A(53Cr), or g values. Kinetics of the last two stages of the reaction have been studied to determine the dependence of reaction rates on acid concentration and to evaluate the activation parameters.

Article information

Article type
Paper

J. Chem. Soc. A, 1968, 501-504

Structure and reactivity of transition-metal complexes with polyatomic ligands. Part V. Electron spin resonance spectra of intermediates and some kinetic results for the acid hydrolysis of [Cr(CN)5NO]3–

J. Burgess, B. A. Goodman and J. B. Raynor, J. Chem. Soc. A, 1968, 501 DOI: 10.1039/J19680000501

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